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Beilstein J. Org. Chem. 2016, 12, 2055–2064, doi:10.3762/bjoc.12.194
Graphical Abstract
Figure 1: Thienyl-bridged oligophenothiazines as topological hybrids of (oligo)phenothiazines and 2,5-di(hete...
Scheme 1: One-pot bromine-lithium-exchange-borylation-Suzuki (BLEBS) synthesis of 7-bromo-substituted phenoth...
Scheme 2: Pseudo five-component Sonogashira-Glaser-cyclization synthesis of thienyl-bridged oligophenothiazin...
Figure 2: Cyclic voltammograms of compounds 3 (recorded in CH2Cl2, T = 293 K, electrolyte n-Bu4N+PF6−, Pt wor...
Figure 3: UV–vis (solid lines) and fluorescence spectra (dashed lines) of the thienyl-bridged oligophenothiaz...
Figure 4: DFT-calculated minimum conformer of the 2,5-bis(terphenothiazinyl)thiophene 3c (calculated with the...
Figure 5: Relevant Kohn–Sham FMOs contributing to the S1 states that are assigned to the longest wavelengths ...
Beilstein J. Org. Chem. 2011, 7, 1499–1503, doi:10.3762/bjoc.7.174
Scheme 1: Concept of a Sonogashira–Glaser coupling sequence.
Scheme 2: Concept of a Sonogashira–Glaser cyclization synthesis of 2,5-di(hetero)arylthiophenes.
Scheme 3: Pseudo five-component Sonogashira–Glaser cyclization synthesis of symmetrical 2,5-di(hetero)arylthi...
Figure 1: Symmetrical 2,5-di(hetero)arylthiophenes 2 synthesized via the one-pot pseudo five-component Sonoga...